A metastable ion has sufficient internal energy to dissociate prior to detection.
2.
UV laser ablation can be combined with a flowing afterglow plasma for mass spectrometry imaging of small molecules . and IR desorption has been combined with a metastable ion source.
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It occurred in air and in nitrous oxide, which possess such metastable ions, and not in atmospheres of argon, carbon dioxide, or helium, which do not.
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Measurements in the negative ion mode are especially favorable when the analyte molecules exhibit a high gas-phase acidity, as it is the case e . g . for carboxylic acids . A direct analysis in real time ( DART ) metastable ion source for plasma based ambient ionization.
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